Evidence for mechanical softening-hardening dual anomaly in transition metals from shock-compressed vanadium

نویسندگان

چکیده

Solids usually become harder and tougher under compression turn softer at elevated temperature. Recently, the compression-induced softening heating-induced hardening dual anomaly was predicted in group VB elements such as vanadium. Here, evidence for this counterintuitive phenomenon is reported. By using accurate high-temperature, high-pressure (HP) sound velocities measured Hugoniot states generated by shockwaves, together with first-principles calculations, we observe not only prominent velocity reduction but also strong enhancement shocked The former corresponds to shear modulus compression, whereas latter reflects reverse heat. These experiments unveil another Young's modulus. Based on experimental theoretical data, infer that vanadium might transition from body-centered cubic into two different rhombohedral phases \ensuremath{\sim}79 116 GPa along Hugoniot, respectively, which implies a dramatic difference static dynamic loading, well significance of deviatoric stress rate-relevant effects HP phase dynamics.

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ژورنال

عنوان ژورنال: Physical Review B

سال: 2021

ISSN: ['1098-0121', '1550-235X', '1538-4489']

DOI: https://doi.org/10.1103/physrevb.104.134102